Zinc

Zinc salts are used in electroplating for the galvanic zinc coating of steel in order to achieve an effective rust prevention. Also in cooling waters, zinc salts are applied as corrosion protection agents.
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Quick navigation: Video tutorial Reaction basis Sample preservation Tips and tricks

How to perform the NANOCOLOR Zinc tube test

Quick navigation: Video tutorial Reaction basis Sample preservation Tips and tricks

Reaction basis

When carrying out the APHA 3500 Zn-F compliant test (REF 985096), Zincon forms a blue color complex with zinc in an alkaline environment, which can be evaluated at 620 nm, the test turns brownish. The also offered Zinc 6 tube test (REF 985042) test is based on a complex formation of 4-(2-pyridylazo) resorcinol with zinc. This test is evaluated by a double determination at 470 and 490 nm.

Fig. 1: Reaction principle in accordance to the APHA conform Zinc determination with Zincon and the reaction principle based on the formation 4-(2-pyridylazo)resorcinol with zinc.

Quick navigation: Video tutorial Reaction basis Sample preservation Tips and tricks

Preservation of samples

After adjusting the pH value to 1–2 with nitric acid, the sample can be preserved for storage for up to 1 month (storage vessel: PE or glass bottle).

Quick navigation: Video tutorial Reaction basis Sample preservation Tips and tricks

Tips and tricks

Decomposition

For the determination of total zinc, decomposition with NANOCOLOR NanOx Metal (REF 918 978) or the crack set (REF 918 08) must be performed prior to analysis. Generally a decomposed blank value should be used as reference.

Common sources of error

When using VISOCOLOR ECO Zinc, attention must be paid to the different sample volumes for visual evaluation (1 mL) and photometric evaluation (5 mL).

Sea water suitability

After dilution (VISOCOLOR ECO Zinc 1+9, NANOCOLOR Zinc 4 1+1, NANOCOLOR Zinc 1+9), the method can also be used for analysis of sea water.

pH

The pH value of the sample solution of 3–10 stated in the instruction leaflets must be complied with. If necessary, adjust the pH with nitric acid or sodium hydroxide.
For acidic, alkaline and buffered samples, measure pH after adding the sample (target: pH 8.5–9.5) and adjust to pH 9 if necessary.

Interferences

Calcium interferes with the detection. For disturbance suppression, use the reagent for lime precipitation (up to 20 g/L Ca²⁺, REF 918939).
Further interfering ions are listed in the instruction leaflets.

Turbidity

Turbid solutions must be filtered prior to the determination of dissolved zinc; turbidity leads to incorrect results: For coarsely dispersed turbidities, use qualitative filter paper (e.g. MN 615), for moderately dispersed turbidities, use glass-fiber paper (e.g. MN 85/70 BF) or membrane filtration set GF/PET 0.45 µm, for finely dispersed turbidities, use membrane filtration kit 0.45 µm or GF/PET 0.45 µm.

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