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| Substances: |
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naphthalene; 2-methylnaphthalene; acenaphthylene; acenaphthene; fluorene; phenanthrene; anthracene; PCB 31; PCB 28; PCB 52; fluoranthene; PCB 101; pyrene; PCB 77; 2-methylfluoranthene; PCB 118; PCB 153; PCB 138; PCB 126; PCB 180; benzo[a]anthracene; chrysene; PCB 169; PCB 194; benzo[b]fluoranthene; benzo[k]fluoranthene; benzo[a]pyrene; dibenzo[ah]anthracene; indeno[1,2,3-cd]pyrene; benzo[ghi]perylene |
| Column: |
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OPTIMA® XLB, 30 m, 0.25 mm, 0.25 μm |
| Phase: |
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OPTIMA® XLB |
| REF number: |
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725850.30 |
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| Conditions: |
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Injection volume: 1 μl, standard 0.005 ng/μl
Injection temperature: 250 °C
Injection pulse: 1.38 bar in 1 min; splittless
Carrier gas: Helium, with purge flow of 60 ml/min
Temperature programm: 40 °C for 2 min, 40 °C -> 240 °C with 30 °C/min, 240 °C for 2 min, 240 °C -> 340 °C with 10 °C/min, 340 °C for 5 min |
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| Detection: |
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GC-MS:
Interface temperature: 280 °C
Ion source temperature: 230 °C
Quadrupol temperature: 150 °C |
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| Author(-s): |
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Centre d´Analyses de Recherche |
| Source: |
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Lab. D´Hydrologie, Illkirch (France), 2007 |
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| Keywords: |
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PAHs; PCBs |
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Chromatogram:
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82% separation of PCB 28 / PCB 31 in less than 10 min:
75% separation of benzo[b]fluoranthene / benzo[k]fluoranthene in 17 min:
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| Legend: |
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1 naphthalene
2 2-methylnaphthalene
3 acenaphthylene
4 acenaphthene
5 fluorene
6 phenanthrene
7 anthracene
8 PCB 31
9 PCB 28
10 PCB 52
11 fluoranthene
12 PCB 101
13 pyrene
14 PCB 77
15 2-methylfluoranthene
16 PCB 118
17 PCB 153
18 PCB 138
19 PCB 126
20 PCB 180
21 benzo[a]anthracene
22 chrysene
23 PCB 169
24 PCB 194
25 benzo[b]fluoranthene
26 benzo[k]fluoranthene
27 benzo[a]pyrene
28 dibenzo[ah]anthracene
29 indeno[1,2,3-cd]pyrene
30 benzo[ghi]perylene
Sample from slag please see Application No.: 212930 |