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Method:
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Matrix
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Application-No.:
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SPE
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oil
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301380
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| Substances: |
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PCB |
| Column: |
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CHROMABOND® SiOH-H2SO4/SA, 3 ml, 500/500 mg,
CHROMABOND® SiOH, 3 ml, 500 mg |
| Phase: |
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CHROMABOND SA/SiOH |
| MN catalog number: |
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730125 |
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| Sample pretreatment: |
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Extract oil-contaminated solids with n-hexane. Homogenise other oil samples and dissolve 1.5 to 2.0 g in 50 ml n-hexane. Water which may cause turbidities can be removed with sodium sulphate. |
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| Conditions: |
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Determination with reference to German Standard DIN 51 527
Column conditioning:
Let 1 ml n-hexane flow through the CHROMABOND® SiOH-H2SO4/SA column.
Sample application:
Aspirate or force 500 μl sample through the CHROMABOND® SiOH-H2SO4/SA column. This phase offers better removal of interfering substances due to sulphonisation. Place CHROMABOND® SiOH-H2SO4/SA column on top of CHROMABOND® SiOH column with the aid of an adaptor (MN-cat. no. 730100) and after at least 30 seconds flush sample into the SiOH column with 2 x 1 ml n-hexane.
Elution:
Elute SiOH column with 3 x 0.5 ml n-hexane; adjust to a suitable concentration for subsequent GC analysis by evaporation of n-hexane in a stream of nitrogen or by dilution with n-hexane. |
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| Author(-s): |
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Macherey-Nagel |
| Source: |
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LC Department |
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| Keywords: |
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PCB; oil |
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| Recovery rates: |
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Compound recovery [%]
PCB 28 99
PCB 52 95
PCB 101 99
PCB 138 94
PCB 153 99
PCB 180 96
PCB 209 101 |
| www.mn-net.com |
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Concerning questions to literature applications please contact the cited author/s. Chemicals mentioned in applications are not manufactured or sold by MACHEREY-NAGEL. Applications mentioned in MACHEREY-NAGEL literature or databases are provided for informational purposes only. MACHEREY-NAGEL does not warrant that all applications have been tested in MACHEREY-NAGEL laboratories using MACHEREY-NAGEL products.
MACHEREY-NAGEL does not warrant the correctness of the applications. |
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